The crash took place in Tolland County around 10:30 a.m., Tuesday, April 11, on Route 32 in Mansfield.
Connecticut State Police said Vanessa Marie Rivero, of the town of Willington in Tolland County, was driving north on Route 32 near Mansfield City Road in a 2022 Volkswagen Jetta when she crossed the double-yellow line and hit a 2012 GMC Sierra head-on, before hitting a guardrail.
Rivero was pronounced dead at the scene, state police said.
The driver of the GMC, New London County resident Theodore Robert Rahmann, age 42, of Lebanon, was transported to Windham Hospital with non-life-threatening injuries.
Any witnesses to the collision are asked to contact Troop C at 860-896-3200.
Click here to follow Daily Voice Amherst and receive free news updates.